Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9781875 | Journal of Physics and Chemistry of Solids | 2005 | 5 Pages |
Abstract
Thermoanalytical characteristics and Raman scattering of high purity sulfur and ternary bulk glasses GexAsxS(100â2x) for x=4-22 at. % were studied. The intermediate phase characterized by vanishing of non-reversing heat flow ÎHnr, i.e. so-called the thermally reversing window was found between mean coordination number ãrãâ¼2.28-2.47. Separated phase of non-crystalline cycloocta-S, manifesting itself by λ-transition at â¼155 °C, was found for glasses with sulfur content higher than â¼80 at.%. Raman spectra of studied Ge-As-S glasses showed different shapes in three different areas according to three distinct phases of network glasses-floppy, intermediate, rigid.
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Materials Science
Electronic, Optical and Magnetic Materials
Authors
E. ÄernoÅ¡ková, T. Qu, S. Mamedov, Z. ÄernoÅ¡ek, J. Holubová, P. Boolchand,