Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9782960 | Materials Chemistry and Physics | 2005 | 7 Pages |
Abstract
The reaction mechanism between hydrous titanium oxide and potassium carbonate at low temperatures was investigated by using XRD, TG, Raman spectra and TEM. In spite of the TiO2/K2O mole ratio in mixtures, the solid state reactions always consisted of two stages. In the first stage (500-640 °C), K2Ti3O7 nanocrystallites with layered structure were formed by the direct reaction of TiO2 and K2CO3 which was clearly confirmed by TG studies in CO2 atmosphere. In the second stage (â¥640 °C), the TiO2/K2O mole ratio in mixtures affected the solid state reaction mechanism remarkably. A new transformation mechanism was found for mixtures with TiO2/K2O mole ratio of 4. The separation between the two stages could be used to control the morphologies and microstructures of potassium titanates by adjusting CO2 partial pressure in atmosphere.
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Authors
Chang Liu, Xiaohua Lu, Gang Yu, Xin Feng, Qitu Zhang, Zhongzi Xu,