Article ID Journal Published Year Pages File Type
9783036 Materials Chemistry and Physics 2005 5 Pages PDF
Abstract
Soluble 5,10,15,20-tetrakis(4-tert-butylphenyl) metalloporphyrins [M(TBP), M = Mg, Cu, Tb(OAc), Lu(OAc), La(OAc)] have been rapidly synthesized by microwave irradiation. They can be prepared from 5,10,15,20-tetrakis(4-tert-butylphenyl) porphyrins [H2(TBP)] or from pyrrole and 4-tert-butylbenzaldehyde with appropriate metal salts. Furthermore, their fluorescent properties have also been investigated. The experimental results reveal that the fluorescent properties of metalloporphyrins depend on their central metals due to heavy-atom effect.
Related Topics
Physical Sciences and Engineering Materials Science Electronic, Optical and Magnetic Materials
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