Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
978327 | Physica A: Statistical Mechanics and its Applications | 2007 | 8 Pages |
Abstract
Electrokinetic phenomena exhibiting discontinuities are described in terms of a stick-slip transition. The flux-force equations are partially linear and in the linear regimes the coefficients satisfy Onsager's reciprocal relations. From an interpretation of existing data on ion exchange membranes we find a linear dependence of the slip length with the surface potential. We conclude that slippage offers an alternative explanation for the so-called anomalous surface conduction, as often found in electrokinetic phenomena. This would imply an enhancement of electrokinetic effects in nanopores.
Related Topics
Physical Sciences and Engineering
Mathematics
Mathematical Physics
Authors
Christophe Cheikh, Ger Koper,