Article ID Journal Published Year Pages File Type
978333 Physica A: Statistical Mechanics and its Applications 2007 22 Pages PDF
Abstract

In this work we analyze time-dependent problems like sound propagation and light scattering in dilute polyatomic gases by using a kinetic model of the Boltzmann equation that replaces the collision operator by a single relaxation-time term which is compatible with Grad's 6-moment approximation. Comparison of the theoretical results with available experimental data in nitrogen, oxygen, carbon dioxide and methane shows that the model equation can be used to describe the acoustic properties and the light scattering spectrum of polyatomic gases in both hydrodynamic and kinetic regimes as long as the external oscillation frequency is smaller than the frequency required for the translational and the internal degrees of freedom to come to thermal equilibrium.

Related Topics
Physical Sciences and Engineering Mathematics Mathematical Physics
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