Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9784039 | Materials Science and Engineering: B | 2005 | 4 Pages |
Abstract
The studies of the (1 â x)Pb(Sc1/2Nb1/2)O3-xPbTiO3 (PSN-PT) single crystals reveal that the chemical and physical properties of the materials are affected by the growth conditions. By the measurements of the dielectric constant as a function of temperature upon cooling, it is found that crystals grown from the same charged stoichiometric composition (x = 0.425), but under different flux environments (i.e. the composition of flux and the flux to PSN-PT ratios are varied), show anomalies (i.e. phase transitions) at different temperatures. This phenomenon is attributed to the complex local chemical structure of the PSN-PT solid solution single crystals with B-site random occupancy of three different cations (Sc3+, Nb5+ and Ti4+). The dielectric and domain structure of the PSN-PT crystals with composition near the morphotropic phase boundary (MPB) are investigated, showing much more complex situations compared with Pb(Sc1/2Nb1/2)O3.
Related Topics
Physical Sciences and Engineering
Materials Science
Electronic, Optical and Magnetic Materials
Authors
Y.-H. Bing, Z.-G. Ye,