Article ID Journal Published Year Pages File Type
9784067 Materials Science and Engineering: B 2005 4 Pages PDF
Abstract
Phase transitions and dielectric properties of the (1 − x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 crystals with x = 0.3-0.5 are studied. The solid solutions in this composition range are shown to be relaxor ferroelectrics. The crystals with low x demonstrate a diffused maximum in the temperature dependences of the dielectric permittivity at Tm. Tm varies with frequency according to the Vogel-Fulcher law. The polarizing microscopy investigations reveal a first-order phase transition from the relaxor phase to the low-temperature ferroelectric phase at TC, which is several degrees below Tm. The permittivity peak in the crystals with x = 0.5 is sharp, and Tm is equal to TC and does not depend on frequency, as is typical of the transition from a ferroelectric to an ordinary paraelectric phase. Nevertheless, the relaxor, but not the paraelectric, phase is observed at T > Tm. This conclusion is confirmed by the observation of the temperature behaviour of complex dielectric permittivity at T > Tm, which is typical of relaxors and related to the existence of polar nanodomains.
Related Topics
Physical Sciences and Engineering Materials Science Electronic, Optical and Magnetic Materials
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