Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
978616 | Physica A: Statistical Mechanics and its Applications | 2006 | 14 Pages |
Abstract
The expression of the free energy density of a classical crystalline system as a gradient expansion in terms of a set of order parameters is developed using classical density functional theory. The goal here is to extend and complete an earlier derivation by Löwen et al. [Europhys. Lett. 9 (1989) 791]. The limitations of the resulting expressions are also discussed including the boundary conditions needed for finite systems and the fact that the results cannot, at present, be used to take into account elastic relaxation.
Related Topics
Physical Sciences and Engineering
Mathematics
Mathematical Physics
Authors
James F. Lutsko,