Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9801311 | Science and Technology of Advanced Materials | 2005 | 4 Pages |
Abstract
A series of crystals of NaxTaS2 with different superconducting transition temperatures (Tc) ranging from 2.0-4.4Â K were obtained by flux method. The structural data deduced from X-ray diffraction pattern shows that the sample has the same structure as 2H-TaS2. Compared with the resistivity curve of un-intercalated sample 2H-TaS2 (Tc=0.8Â K, TCDWâ70Â K), no signal of charge density wave (CDW) was observed in our present samples Na0.1TaS2. It is thus concluded that there is a competition between the superconductivity and the CDW. With the increase of sodium content, the rise of Tc in NaxTaS2 is caused mainly by the suppression to the CDW in 2H-TaS2, and the conventional rigid band model for layered dichalcogenide may be inadequate to explain the changes induced by the slight intercalation of sodium in 2H-TaS2.
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Authors
L. Fang, P.Y. Zou, Y. Wang, L. Tang, Z. Xu, H. Chen, C. Dong, L. Shan, H.H. Wen,