Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9803389 | Journal of Alloys and Compounds | 2005 | 8 Pages |
Abstract
Structural properties of model palladium-cobalt clusters with various composition have been analysed. Their structure is optimised using Sutton-Chen potentials and Monte-Carlo procedure. Radial distribution functions and extended X-ray absorption fine structure (EXAFS) spectra were averaged over atomic configurations along Molecular Dynamics (MD) run. Applicability of the cumulant expansion method for studies of such nanoclusters is discussed. It has been found that shape of EXAFS oscillations of Pd K-edge in the k range 5-8âÃ
â1 strongly depends on composition of a cluster. The same effect is visible for EXAFS spectra of Co K-edge in the range 4-7âÃ
â1. These results are compared to the experimental data obtained for the sample of 50âat.%Pd-50âat.%Co supported on silica.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
BogusÅaw Mierzwa,