| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9803955 | Journal of Alloys and Compounds | 2005 | 6 Pages |
Abstract
Multicomponent vanadate Zn3Fe4V6O24 has been obtained by the solid-state reaction method using stoichiometric mixtures of the ZnO, Fe2O3 and V2O5 oxides. The neutron diffraction patterns of Zn3Fe4V6O24 registered at 10 and 290 K have been investigated. This material, crystallizing in the triclinic space group P1¯, has a complicated structure with two metal ion systems. Down to the temperature of 10 K no long-range magnetic order has been observed. Essential differences in the positions of metal ions were observed relative to these obtained in similar systems (β-Cu3Fe4V6O24 and Mn3Fe4V6O24) investigated by X-ray diffraction method. In contrast to previously studied vanadates (Zn2FeV3O11 and Mg2FeV3O11) no disordering of metal ions in their corresponding subsystems was detected.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
N. Guskos, A. Bezkrovnyi, J. Typek, N.Yu. Ryabova, A. Blonska-Tabero, M. Kurzawa, M. Maryniak,