Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9808596 | Materials Letters | 2005 | 4 Pages |
Abstract
A new zinc-cobalt phosphate compound [Zn(4âx)Cox(PO4)2(HPO4)][C3H4N2]3 (xâ0.25) (1) has been hydrothermally synthesized in the presence of imidazole as the template and crystallizes in the triclinic space group Pâ1 with crystal data a=9.6077(7) Ã
, b=9.8674(7) Ã
, c=12.3793(9) Ã
, α=77.569(4)°, β=78.040(4)°, γ=68.191(4)°, V=1053.52(13) Ã
3, Z=2. Compound 1 exhibits an infinite two-dimensional layered structure, which is built up of {M8P6O23} structural unit formed by vertex-sharing MO4, MO2N2, MO3N, PO4 and PO3(OH) (M=Zn, Co) moieties. A study of magnetic measurements indicates compound 1 has the well antiferromagnetic behavior.
Related Topics
Physical Sciences and Engineering
Materials Science
Nanotechnology
Authors
Li Liu, He Meng, Guanghua Li, Yanjie Cui, Hong Ding, Yan Xing, Wenqin Pang,