Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9817642 | Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms | 2005 | 4 Pages |
Abstract
We have pushed the limits of X-ray absorption spectroscopy under high pressure in order to study the stability of the Ba intercalated silicon clathrate. EXAFS experiments at the Ba K-edge have been performed in the step by step mode up to a pressure of 14.5Â GPa using the Paris-Edinburgh cell with sintered diamond anvils. XANES experiments at the Ba L-III edge were done in an energy dispersive set-up using hollowed diamond anvil cells up to a pressure of 20Â GPa. Combining the obtained results with high pressure X-ray diffraction we demonstrate the high stability of the Ba intercalated silicon clathrates. Our conclusions could be extended to other clathrate systems.
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Authors
A. San-Miguel, P. Toulemonde, A. Merlen, B. Masenelli, F. Tournus, T. Kume, S. Le Floch, A. Aouizerat, S. Pascarelli, G. Aquilanti, O. Mathon, T. Le Bihan, J.-P. Itié, S. Yamanaka,