Article ID Journal Published Year Pages File Type
9830117 Journal of Crystal Growth 2005 18 Pages PDF
Abstract
Contrary to conventional observations, in a turbulent solution flow the average step bunch width and height were found to reach limits as bunches propagate along the face. These limits decrease when the flow rate increases from ∼60 to 200 cm/s. The phenomenon is explained by the turbulent nature of the solution flow. In this flow, due to penetration of turbulent eddies, diffusivity within the viscous solution boundary layer, D=D0+0.5 uτ y, quickly increases with the distance y from the interface since the friction velocity, uτ, reaches several cm/s. Therefore, molecular diffusivity, D0 ≅ 10−5 cm2/s, is significant only within the ∼20-40 nm thick solution layer over the interface. As the flow rate increases, the turbulent mixed solution approaches the growing stepped crystal face closer and shrinks the range within which steps interact with one another through their diffusion fields. This weak interaction results in step splitting.
Related Topics
Physical Sciences and Engineering Physics and Astronomy Condensed Matter Physics
Authors
, , ,