Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9952645 | Thermochimica Acta | 2018 | 16 Pages |
Abstract
The volumetric properties and isentropic compressibilities of binary mixtures of formamide (FA) with 2-dialkylaminoethanols viz. 2-dimethylaminoethanol (2-DMAE) and 2-diethylaminoethanol (2-DEAE) were evaluated over the entire composition range at 303.15, 313.15 and 323.15âK and at atmospheric pressure. The excess partial molar volumes (V¯m,1E and V¯m,2E), excess isentropic compressibility (κsE), excess partial molar compressions (K¯s,m,1E and K¯s,m,2E) are deduced. The partial molar volumes (V¯m,1â and V¯m,2â), partial molar compressions (K¯s,m,1â and K¯s,m,2â), excess partial molar volumes (V¯m,1âE and V¯m,2âE), and excess partial molar compressions (K¯s,m,1âE and K¯s,m,2âE), at infinite dilution, over the entire composition range are also calculated. The knowledge of the volumetric properties and molar compression aids to understand specific molecular interactions existing between the FA and 2-DMAE/2-DEAE molecules of the binary system. The strength of intermolecular interactions in these mixtures follows the order: FAâ+â2-DEAEâ>âFAâ+â2-DMAE. The required experimental data are used from our earlier work on the volumetric and acoustic study published in J. Mol. Liqs. 219 186 (2016).
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Fluid Flow and Transfer Processes
Authors
Anjali Awasthi, Reetesh Srivastava, Vrijesh K. Pandey, Vikash Verma, Aashees Awasthi,