Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9953413 | Polymer Degradation and Stability | 2018 | 59 Pages |
Abstract
A novel oligomer (PFDCHQ) based on 9,10-dihydro-9-oxa-10-phosphaphenanthrene â10-oxide (DOPO) and ferrocene groups was synthesized successfully, aiming at improving the flame retardant efficiency of diglycidyl ether of bisphenol A epoxy resin (DGEBA). FTIR, 1H NMR and 31P NMR were used to confirm the chemical structure of PFDCHQ. The high char yields of 60.3â¯wt% and 20.1â¯wt% were obtained for PFDCHQ from TGA results in nitrogen and air atmosphere, respectively. The thermal degradation mechanism of PFDCHQ was investigated by TG-FTIR and Py-GC/MS. The limiting oxygen index (LOI) of EP-5 with 5â¯wt% loading of PFDCHQ increased to 32.0% and the UL-94 V-0 rating was achieved, showing a notable blowing-out effect. In contrast to EP-0, the peak of the heat release rate (pHRR) and total heat release (THR) of EP-5 decreased by 18.0% and 10.3%. The flame retardant mechanism of PFDCHQ in epoxy resin was studied by TG-FTIR, SEM and Raman. SEM and Raman results indicated the formation of coherent and dense char residue with high degree of graphitization due to the incorporation of PFDCHQ. In UL-94, the blowing-out effect dominantly accounted for the enhanced flame retardancy in combination with optimized char structure. Furthermore, the addition of PFDCHQ improved the Young's modulus compared to EP-0.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yi Wen, Zhou Cheng, Wenxiong Li, Zhi Li, Duijun Liao, Xiaoping Hu, Ning Pan, Deyi Wang, T. Richard Hull,