| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10266987 | Electrochemistry Communications | 2005 | 6 Pages |
Abstract
By removing complications caused by transport, the surface confinement of substrate and product members of a redox pair simplifies the relationships governing transient electrode reactions, often permitting a mathematical solution even when the voltammetry is kinetically controlled. Here a non-simulative study is undertaken and applied to linear-potential-scan chronoamperometry and cyclic voltammetry. Exact equations are rederived for reversible and irreversible cases; novel quasireversible results are in the form of integrals that may be evaluated numerically.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Jan C. Myland, Keith B. Oldham,