Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10266995 | Electrochemistry Communications | 2005 | 5 Pages |
Abstract
TEMPO electro-mediated oxidation of alcohols has been investigated in aqueous and hydro-organic media. Mono- and poly-saccharides, aryl alcohols and heterocyclic alcohols were converted into the corresponding carbonyls in good chemical and Faradaic yields. In both solvents, the electrochemically generated TEMPO+ was used in catalytic amount and the kinetics was found to be controlled by the diffusion step.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Denis Liaigre, Tony Breton, El Mustapha Belgsir,