Article ID Journal Published Year Pages File Type
10376759 Journal of Colloid and Interface Science 2012 9 Pages PDF
Abstract
► We studied the reaction of 4-nitrobenzenediazonium ions with cyclodextrins at pH < 3. ► In the absence of cyclodextrin, the main reaction pathway is heterolytic DN + AN mechanism. ► Addition of cyclodextrin increases the rate of reaction and promotes homolytic dediazoniation. ► Addition of sodium dodecylsulfate blocks the cyclodextrin cavity inhibiting the reaction.
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Related Topics
Physical Sciences and Engineering Chemical Engineering Colloid and Surface Chemistry
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Cyclodextrin induced switch between heterolytic and homolytic dediazoniation mechanisms
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