Article ID Journal Published Year Pages File Type
10377026 Journal of Colloid and Interface Science 2011 10 Pages PDF
Abstract
► Integral molar enthalpy is a proper variable to describe heat of adsorption under supercritical conditions. ► The strong confinement results in higher heat of adsorption. ► The behaviour of surface excess in a cylinder under supercritical conditions is similar to that on a flat surface. ► Supercritical adsorption is a densification process reflected by the behaviour of layer compressibility.
Related Topics
Physical Sciences and Engineering Chemical Engineering Colloid and Surface Chemistry
Authors
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