Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10377527 | Journal of Colloid and Interface Science | 2005 | 6 Pages |
Abstract
We apply density functional theory to investigate changes in the phase behavior of a fluid caused by the presence of mobile ions inside the pore. The approach has been based on the fundamental measure density functional theory and on the theory of nonuniform electrolytes developed recently by O. Pizio, A. Patrykiejew, S. SokoÅowski [J. Chem. Phys. 121 (2005) 11,957]. We have evaluated capillary condensation phase diagrams for pores of different widths and for different concentrations of confined ions. The calculations have demonstrated that the presence of ions leads to lowering the critical temperature and to an increase of the value of the chemical potential at the capillary condensation point.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Colloid and Surface Chemistry
Authors
M. Borówko, K. Bucior, S. SokoÅowski, T. Staszewski,