Article ID Journal Published Year Pages File Type
10377945 Journal of Colloid and Interface Science 2005 7 Pages PDF
Abstract
The boundary effect on the dynamic electrophoretic behavior of a charged entity is examined by considering a sphere in a spherical cavity. The present study extends previous analysis to the case of an arbitrary level of electrical potential where the effect of double-layer distortion can be significant. The governing equations are solved numerically based on a pseudo-spectral method, which is found to be sufficient in solving the corresponding electrophoresis problem when a static electric field is applied. The result of numerical simulation reveals that as the size of a cavity decreases, both the magnitude of the mobility and the inertial force acting on a particle decrease accordingly. Also, while the distortion of the ionic cloud should not be ignored, in general, when the surface potential of a particle is high, its influence on the magnitude and on the phase angle of the mobility is alleviated by the presence of the cavity.
Related Topics
Physical Sciences and Engineering Chemical Engineering Colloid and Surface Chemistry
Authors
, , ,