Catalytic dehydration of ethanol using transition metal oxide catalysts

The aim of this work is to study catalytic ethanol dehydration using different prepared catalysts, which include Fe2O3, Mn2O3, and calcined physical mixtures of both ferric and manganese oxides with alumina and/or silica gel. The physicochemical properties of these catalysts were investigated via X-ray powder diffraction (XRD), acidity measurement, and nitrogen adsorption-desorption at −196 °C. The catalytic activities of such catalysts were tested through conversion of ethanol at 200-500 °C using a catalytic flow system operated under atmospheric pressure. The results obtained indicated that the dehydration reaction on the catalyst relies on surface acidity, whereas the ethylene production selectivity depends on the catalyst chemical constituents.