| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10578121 | Polyhedron | 2012 | 8 Pages |
Abstract
A novel Co(III) salt of the formula [Co(en)2(N3)2]·ClO4 (1) has been obtained and structurally characterized by the X-ray crystallography method. Spectroscopic (FT-IR, NIR-Vis-UV) studies have been performed for the low-spin [Co(en)2(N3)2]·ClO4 (1), [Co(en)2CO3]·ClO4 (2) and [Co(bpy)2CO3]·NO3·5H2O (3) complexes. Absorption bands have been assigned to the electronic transitions, depending on the symmetry of the chromophores.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Agnieszka Wojciechowska, Danuta DobrzyÅska, Jan Janczak,