Article ID Journal Published Year Pages File Type
10578132 Polyhedron 2005 6 Pages PDF
Abstract
Aqueous system Zn(II)-tn-[Ni(CN)4]2− (tn = 1.3-diaminopropane) in contact with air captured carbon dioxide yielding coordination polymer Zn2(tn)2(CO3)Ni(CN)4 · H2O. The carbonato ligand coordinates three zinc atoms by an unusual mode, two by an unidentate and one by a bidentate fashion with one oxygen donor atom forming two ZnO coordination bonds.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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