Article ID Journal Published Year Pages File Type
10578141 Polyhedron 2005 9 Pages PDF
Abstract
Treatment of M(N(SiMe3)2)2(THF)2 (M = Sr, Ba) with tetraglyme, triglyme or N,N,N′,N″,N″-pentamethyldiethylenetriamine (PMDETA) followed by 3,5-di-tert-butylpyrazole (2 equiv) afforded monomeric complexes of the formula M(tBu2pz)2(L). These complexes possess monomeric structures with terminal η2-pyrazolato ligands, and are of relevance to the development of volatile group 2 film growth precursors.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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