| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10578143 | Polyhedron | 2005 | 8 Pages |
Abstract
New multinuclear titanium(IV) oxo carboxylates of the general formula [Ti8O8(OOCR)16] (where R = But (1), CH2But (2), C(CH3)2Et (3)) have been synthesized and characterized by single-crystal X-ray diffraction and spectroscopic techniques. Titanium atoms form oligomeric rings [Ti8(μ2-O)8], where each Ti cation is surrounded by six oxygen atoms (two μ2-oxo and four μ-carboxylato bridges).
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis, crystal structures and spectroscopic characterization of [Ti8O8(OOCR)16] (where RÂ =Â But, CH2But, C(CH3)2Et)](/preview/png/10578143.png "First Page Preview: Synthesis, crystal structures and spectroscopic characterization of [Ti8O8(OOCR)16] (where RÂ =Â But, CH2But, C(CH3)2Et)")
Authors
P. Piszczek, M. Richert, A. Grodzicki, T. GÅowiak, A. Wojtczak,