| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10578235 | Polyhedron | 2011 | 9 Pages |
Abstract
⺠We have synthesised and structurally characterised four new metal complexes containing the polydentate ligands system POPYH4. ⺠The unusual Zn(II) complex has been shown to consists of an unusual tetra-zinc core supported by three POPYH ligands each one of which links two adjacent zinc centres through two oxygen and two nitrogen donor atoms. ⺠In contract the Ni(II) and Pd(II) complexes described posses central square planar geometry in which the POPYH ligand are coordinated through the two deprotonated amido nitrogen atoms, the pyridine nitrogen.
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Authors
Yolanda Pérez, Andrew L. Johnson, Paul R. Raithby,