In depth investigation of the synthesis, structural, and spectroscopic characterization of a high pH binary Co(II)-N,N-bis(phosphonomethyl)glycine species. Association with aqueous speciation studies of binary Co(II)-(carboxy)phosphonate systems

Article ID	Journal	Published Year	Pages	File Type
10578253	Polyhedron	2011	11 Pages	PDF

Abstract

âº pH-specific synthesis affords new high pH structural variant in Co(II)-NTA2P system. âº (NH4)3[Co(C4H6O8NP2)(H2O)2]Â·4H2O can be precursor to new Co(II)-organophosphonates. âº Aqueous speciation reflects diversity of Co(II) species in Co(II):NTAxP systems. âº Structure-activity in Co(II)-NTA2P system link high and low pH structural variants. âº pH-dependent reactivity supports magnetostructural relations in Co(II)-NTA2P system.

Keywords

Magnetic properties Structure–reactivity Cobalt(II)

Related Topics

Physical Sciences and Engineering Chemistry Inorganic Chemistry

Preview

In depth investigation of the synthesis, structural, and spectroscopic characterization of a high pH binary Co(II)-N,N-bis(phosphonomethyl)glycine species. Association with aqueous speciation studies of binary Co(II)-(carboxy)phosphonate systems

Authors

M. Menelaou, M. Daskalakis, A. Mateescu, C.P. Raptopoulou, A. Terzis, C. Mateescu, V. Tangoulis, T. Jakusch, T. Kiss, A. Salifoglou,