Article ID Journal Published Year Pages File Type
10578343 Polyhedron 2012 8 Pages PDF
Abstract
The synthesis of the monometallic mixed ligand [Os(dpop′)(tppz)](PF6)2 complex is described, and it is used as a building block for Os(II)/Os(II) and Ru(II)/Os(II) bimetallic complexes. UV-Vis absorption spectra and electrochemical results are presented. NMR spectra are used to verify the structure and purity of the synthetically challenging complexes.
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Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
The syntheses and characterization of Os(II) and Ru(II)/Os(II) bimetallic complexes with dipyrido(2,3-a:3′,2′-j)phenazine (dpop′) and the bridging ligand 2,3,5,6-tetra(2-pyridyl)-pyrazine (tppz)
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