Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10578347 | Polyhedron | 2012 | 9 Pages |
Abstract
Through the interactions of homoleptic [Hg(EPh)2] molecules and [Cd(EPh)4]2â anions (E = S, Se) as metalloligands with [M(PPh3)2Cl] or [M(PPh3)2NO3] (M = Cu, Ag), series of new heterobimetallic Cd(Hg)/Cu(Ag)/S(Se) complexes including neutral trinuclear [Hg(μ-EPh)2{CuCl(PPh3)2}2] and [Cd(μ-EPh)4{M(PPh3)2}2] and heptanuclear [Cd3(μ-EPh)6(μ3-EPh)4(AgPPh3)4] have been isolated and characterized. Their molecular structures and spectroscopic properties of these heterobimetallic complexes have been presented in this paper.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Chao Xu, Jing-Jing Zhang, Tai-Ke Duan, Qun Chen, Wa-Hung Leung, Qian-Feng Zhang,