Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10578356 | Polyhedron | 2012 | 6 Pages |
Abstract
The synthesis and characterisation of iron(II) and ruthenium(II) complexes of 4â²-amino-2,2â²:6â²,2â³-terpyridines, 4â²-Rtpy with R = PhNH (1), 4-MeOC6H4NH (2) and 3,5-Me2C6H3NH (3) are described, along with the single crystal structures of [Fe(1)2][PF6]2·MeCN, [Fe(2)2][PF6]2·MeCN and [Ru(2)2][PF6]2. The solid state structures are analysed in terms of the way in which the presence of the pendant substituents disrupt the Ï-stacking interactions between tpy units of adjacent cations.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yaqiu Tao, Edwin C. Constable, Catherine E. Housecroft, Markus Neuburger,