| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10578393 | Polyhedron | 2011 | 8 Pages |
Abstract
⺠The crystal and electronic structures of the four isothiocyanate manganese(II) complexes have been determined and employed for discussion of the bonding properties. ⺠The 10 Dq and Racah B, C parameters were calculated from electronic spectra of the complexes. The values of nepheloauxetic parameters confirm ionic character of Mn-ligands Ï bonds in the complexes. ⺠All the single crystals of the complexes are paramagnets with small increasing orbital contribution in the sequence of ligands: pyridine, γ-picoline, 2-(hydroxymethyl)pyridine.
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
J.G. MaÅecki, B. Machura, A. Åwitlicka, T. GroÅ, M. BaÅanda,