Article ID Journal Published Year Pages File Type
10578402 Polyhedron 2011 7 Pages PDF
Abstract
► We have measured the competition of MTO and OsO4 toward pyridine. ► We have measured the coordination ability of MTO and OsO4 toward lewis bases. ► The equilibrium constant for the reaction OsO4·L + MTO = MTO·L + OsO4, has been measured. ► An acceptable linear relationship between ΔH and ΔS is observed.
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Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Competition of methyltrioxorhenium (MTO) with osmium tetroxide (OsO4) for pyridines binding: Ligand binding assay
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