Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10578410 | Polyhedron | 2011 | 7 Pages |
Abstract
⺠Cyclam macrocycle can be functionalized by consecutive addition four methyl acrylates followed by condensation with ethylenediamine. ⺠The tetrafunctionalized cyclam condensates with 2,6-aryl-dialdehydes to form three isomeric tricyclic ligands. ⺠Manganese(II) incorporation into tricyclic ligand leads to dimanganese(II) complex and protonation of cyclam core. ⺠The dimanganese(II) complex is valuable synthon to obtain trinuclear mixed-metal-ion complexes.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
PaweÅ Subik, Agata BiaÅoÅska, StanisÅaw WoÅowiec,