Article ID Journal Published Year Pages File Type
10578410 Polyhedron 2011 7 Pages PDF
Abstract
► Cyclam macrocycle can be functionalized by consecutive addition four methyl acrylates followed by condensation with ethylenediamine. ► The tetrafunctionalized cyclam condensates with 2,6-aryl-dialdehydes to form three isomeric tricyclic ligands. ► Manganese(II) incorporation into tricyclic ligand leads to dimanganese(II) complex and protonation of cyclam core. ► The dimanganese(II) complex is valuable synthon to obtain trinuclear mixed-metal-ion complexes.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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