| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10578434 | Polyhedron | 2005 | 10 Pages |
Abstract
A series of titanium-pyrrolyl compounds, namely [Me2Si(C5Me4)2]Ti(NC4H4)X (XÂ =Â H, Me, Cl, NC4H4) and [Me2Si(C5Me4)(C5Me3CH2)]Ti(NC4H4) has been synthesized and structurally characterized by X-ray diffraction. Analysis of the TiNC4H4 bond lengths in these complexes indicates that pyrrolyl does not, by comparison to dialkylamido, act as an efficient Ï-donor ligand.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Ansa-titanocene pyrrolyl complexes: The synthesis and structural characterization of [Me2Si(C5Me4)2]Ti(NC4H4)X (XÂ =Â H, Me, Cl and NC4H4) and [Me2Si(C5Me4)(C5Me3CH2)]Ti(NC4H4)](/preview/png/10578434.png "First Page Preview: Ansa-titanocene pyrrolyl complexes: The synthesis and structural characterization of [Me2Si(C5Me4)2]Ti(NC4H4)X (XÂ =Â H, Me, Cl and NC4H4) and [Me2Si(C5Me4)(C5Me3CH2)]Ti(NC4H4)")
Authors
Hyosun Lee, Jeffrey B. Bonanno, Brian M. Bridgewater, David G. Churchill, Gerard Parkin,