Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10578437 | Polyhedron | 2005 | 16 Pages |
Abstract
The higher deuterated n-alkyl hydrides [W{(η-C5H4)CMe2(η-C5H4)}(R)H](R = {(CH2)nCH3}, n = 1-4) and [W{(η-C5H4)CMe2(η-C5H4)}{CD2CD3}H] undergo hydrogen/deuterium exchange processes under thermal conditions and in every case of all the possible alkyl hydrogens of the alkyl groups R only H/D exchange with the α-CH2 methylene hydrogens was observed.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Malcolm L.H. Green, Stephen L.J. Conway, Linda H. Doerrer,