Spectroscopic and crystal structure data of the alkali-, thallium (I) and onic-salts of dimethyl-N-trichloracetylamidophosphate

This article outlines alkali-, thallium (I) and onic-salts of dimethyl-N-trichloracetylamidophosphate [HL]. A brief description of the syntheses and IR and NMR spectroscopic studies of seven carbacylphosphortriamide compounds are given. All synthesized compounds have been structurally characterized. It was determined that the type of metal-ligand interaction in Na[L], Rb[L] and Tl[L] was ionic. IR spectroscopic and X-ray structure analysis of the [SbPh4L] complex determined the preferable donor center (phosphoryl oxygen atom in the L−).