Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10578452 | Polyhedron | 2005 | 7 Pages |
Abstract
This work describes the synthesis of the low-weight Pd(II) coordination polymers [(N3)(HL)Pd{Pd3(μ-N3)(μ-L)5}10(μ-L)2Pd(L)(HL)] {L = Pzâ (1); mPzâ (2), IPzâ (3)} and [(N3)(HPz)Pd{Pd6(μ-N3)2(μ-Pz)5(μ-L)5}10(μ-L)2Pd(Pz)(HPz)] {L = mPzâ (4), dmPzâ (5); IPzâ (6)} {L = pyrazolate (Pzâ), 4-methylpyrazolate (mPzâ), 4-iodopyrazolate (IPzâ), 3,5-dimethylpyrazolate (dmPzâ)}. Some structures have been suggested on basis of IR, NMR, UV-VIS and osmometry studies.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
A.V.G. Netto, R.C.G. Frem, A.E. Mauro,