| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10578453 | Polyhedron | 2005 | 8 Pages |
Abstract
Lithium amides Li[N(SiMe3)(R)] (RÂ =Â -SiPh2tBu and adamantyl) have been treated with anhydrous ZnCl2 and HgBr2 to yield the corresponding homoleptic metal silylamides. All complexes are fully characterized and are monomeric as determined by single crystal X-ray crystallography. The adamantyl-containing compounds differ significantly in their solid-state structures. Reactivities of these new compounds with CO2 are also presented.
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yongjun Tang, Ana M. Felix, Brian J. Boro, Lev N. Zakharov, Arnold L. Rheingold, Richard A. Kemp,