Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10578458 | Polyhedron | 2005 | 7 Pages |
Abstract
This paper reports the synthesis and characterisation by solid-state 111Cd NMR of cadmium 2,x-pyridine-dicarboxylates. 111Cd NMR chemical shift is sensitive to the relative position of both carboxylates. The crystal and molecular structure of the seven-coordinated cadmium complex, [Cd(2,4-pyridinedicarboxylato)(H2O)3] · 1/2H2O is reported. This structure helps in the understanding of how to correlatate coordination and geometry with 111Cd chemical shifts. Anisotropy data is reported.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Guillermo Mendoza-DÃaz, Graciela Rigotti, Oscar E. Piro, Elsa E. Sileo,