| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10578464 | Polyhedron | 2005 | 6 Pages |
Abstract
A series of tetranuclear heterothiometallic clusters [Et4N]2[(MS4)2Au2(dppe)] (1: MÂ =Â Mo; 2: MÂ =Â W), [PPh4]2[(MoOS3)2Au2(dppe)] (3), [Et4N]2[(WOS3)2Au2(dppe)] (4), [Et4N]2[(MS4)2Au2(dppf)] (5: MÂ =Â Mo; 6: MÂ =Â W) and [Et4N]2[(MOS3)2Au2(dppf)] (7: MÂ =Â Mo; 8: MÂ =Â W) have been synthesized. In the molecular structures of 2, 4 and 6, the two linear M/Au/S units are linked via bidentate phosphines, dppe or dppf. These clusters all exhibit room-temperature luminescence in the solid state.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Li Song, Sheng-Qing Xia, Sheng-Min Hu, Shao-Wu Du, Xin-Tao Wu,