| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10578486 | Polyhedron | 2005 | 9 Pages |
Abstract
Two different sets of hexacoordinated cobalt(II) and cobalt(III) pseudohalide complexes have been prepared in combination with tetra- and tridentate N-donor Schiff bases, respectively. X-ray diffraction measurements of one representative member from each group, viz., trans-[Co(pfpd)(NCS)2] (1c) and mer-[Co(pbed)(N3)3] (2b) are done to define coordination sphere. All the complexes display intraligand 1(Ï-Ï*) fluorescence and intraligand 3(Ï-Ï*) phosphorescence in glassy solutions (MeOH at 77 K).
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Sk Hafijur Rahaman, Habibar Chowdhury, Doyel Bose, Rajarshi Ghosh, Chen-Hsing Hung, Barindra Kumar Ghosh,