| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10578528 | Polyhedron | 2005 | 8 Pages |
Abstract
The redox reaction is first order in both AuCl4- and histidine. An inner-sphere mechanism is suggested. The rate determining steps in the mechanism are shown. It is shown that the intermediate C1 decomposes at a rate about 103 faster than the rate of decomposition of C. It is also shown that the rate of formation of these intermediates (outer-sphere mechanism) cannot be rate determining.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Vimal Soni, R.S. Sindal, Raj N. Mehrotra,