| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10578530 | Polyhedron | 2005 | 11 Pages |
Abstract
Various routes to Cu(II) and Ba fluorocarboxylate derivatives as possible metal organic deposition (MOD) precursors of high Tc superconductors have been investigated. Reactions between copper(II) trifluoroacetate and functional alcohols such as isopropoxyethanol or dimethylaminoethanol afforded a complex Cu2(TFA)4(OHC2H4OiPr)2 or a carboxylatoalkoxide Cu4(μ,η2-TFA)4(μ3,η2-OC2H4NMe2)4, respectively. The reaction between Ba trifluoroacetate and N-methyldiethanolamine (mdeaH2) provided the first example of an ionic Ba TFA derivative
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Jianyong Zhang, Liliane G. Hubert-Pfalzgraf, Dominique Luneau,