Article ID Journal Published Year Pages File Type
10578566 Polyhedron 2005 6 Pages PDF
Abstract
The synthesis, derivatization and transition metal complexes of Ph2PO(C6H10)OPPh2 (1) are presented. The reaction of 1 with Mo(CO)6 in the presence of TMNO · 2H2O gives a cubane-shaped tetranuclear molybdenum(V) complex, [Mo4O4(μ3-O)4(μ-O2PPh2)4] (6) due to water assisted cleavage of P-O bonds.
Keywords
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
A new diphosphinite derived from cyclohexane-1,4-diol: oxidation reactions, metal complexes, P-O bond cleavage and X-ray crystal structures of Ph2P(E)O(C6H10)OP(E)Ph2 (E = S, Se)
Authors
, , ,