| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10578591 | Polyhedron | 2005 | 9 Pages |
Abstract
New dinuclear uranyl complexes are formed with pyridine-2,6-dicarboxylic acid in the presence of tertiary amines. The two uranyl ions, each of them bound to the nitrogen and two carboxylate groups of the ligand, are bridged by μ-η2,η2-peroxide, μ2-hydroxide or μ2-methoxide ions. The latter case is the first example of uranyl-bridging methoxide ions to be crystallographically characterized.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Bernardo Masci, Pierre Thuéry,