| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10578601 | Polyhedron | 2005 | 7 Pages |
Abstract
The synthesis, spectroscopic (1H NMR, IR, UV-Vis), electron-transfer properties and catalytic reactivity of new bis(N-aryl-3,5-Bu2t-salicylaldiminato)palladium(II) complexes are presented. Introduction of t-Bu groups on the salicylic ring increases their catalytic activity towards hydrogenation of nitrobenzene in DMF. The oxidation of the complexes with (NH4)2Ce(NO3)6 generates Pd(II)-phenoxyl radical complexes and nitroxide radicals.
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Authors
Veli T. Kasumov, EÅref TaÅ, F. Köksal, Åeniz Ãzalp-Yaman,