Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10578624 | Polyhedron | 2005 | 9 Pages |
Abstract
We have synthesized and characterized two new nickel (II) complexes, bis(N-R-1-phenylethyl- or N-2-propyl-3,5-dichlorosalicydenaminato)nickel (II), which exhibit a thermally induced structural phase transition and negative solvatochromism. After UV light irradiation, we have successfully observed slight spectral changes in the Ï-Ï* region due to a conformational change of the chiral ligands caused by photochromic solute (4-hydroxyazobenzene) induced solvatochromism.
Related Topics
Physical Sciences and Engineering
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Inorganic Chemistry
Authors
Takashiro Akitsu, Yasuaki Einaga,