| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10578775 | Polyhedron | 2005 | 7 Pages |
Abstract
The polymeric sheet structure of [WS4Ag2(Hmimt)2]n is the first example of a complex in which a tetrathiometalate coordinates in a monodentate fashion to another metal. Silver is in two very different coordination environments, one with only [WS4]2â ligands and the other with both bridging and terminal thione ligands as well as the monodentate [WS4]2â.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis and characterization of the bimetallic polymers [MS4Ag2(Hmimt)2]n (where M = Mo or W, Hmimt = 1-methylimidazoline-2(3H)-thione): crystal structures of [WS4Ag2(Hmimt)2]n and [Ag2I2(Hmimt)]n](/preview/png/10578775.png "First Page Preview: Synthesis and characterization of the bimetallic polymers [MS4Ag2(Hmimt)2]n (where M = Mo or W, Hmimt = 1-methylimidazoline-2(3H)-thione): crystal structures of [WS4Ag2(Hmimt)2]n and [Ag2I2(Hmimt)]n")
Authors
Azizolla Beheshti, William Clegg, Neil R. Brooks, Fatemeh Sharafi,